Ordering Phenomena in Rare-Earth Nickelate Heterostructures

di Matthias Hepting (Autore)

Springer International Publishing AG, 2017

This thesis presents an experimental study of ordering phenomena in rare-earth nickelate-based heterostructures by means of inelastic Raman light scattering and elastic resonant x-ray scattering (RXS). Further, it demonstrates that the amplitude ratio of magnetic moments at neighboring nickel sites can be accurately determined by RXS in combination with a correlated double cluster model, and controlled experimentally through structural pinning of the oxygen positions in the crystal lattice. The two key outcomes of the thesis are: (a) demonstrating full control over the charge/bond and spin order parameters in specifically designed praseodymium nickelate heterostructures and observation of a novel spin density wave phase in absence of the charge/bond order parameter, which confirms theoretical predictions of a spin density wave phase driven by spatial confinement of the conduction electrons; and (b) assessing the thickness-induced crossover between collinear and non-collinear spin structures in neodymium nickelate slabs, which is correctly predicted by drawing on density functional theory.

• Autore: Matthias Hepting
• Editore: Springer International Publishing AG
• Collana: Springer Theses
• Anno: 2017
• Rilegatura: Hardback
• Pagine: 147 p.
• Dimensioni: 235 x 155 mm
• EAN: 9783319605302

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