S Sulfur-Nitrogen Compounds: Part 10a: Compounds with Sulfur of Oxidation Number II

di Norbert Baumann (Autore)

Hans-Jürgen Fachmann (Autore)

Reimund Jotter (Autore)

Springer-Verlag Berlin and Heidelberg GmbH & Co. KG, 2013

The present volume describes acyclic Sulfur-nitrogen compounds with sulfur of the oxida- tion number II. The first chapter deals with sulfur imide (S=NH), N-organyl-sulfur imides (S=NR, R = or- ganyl), and metal complexes of sulfur imides. N-Organyl-sulfur imides have not been isolated, but they can be trapped, for example, by cycloaddition and stabilized by coordination to transi- tion metals. 11 The following chapter present a detailed survey of other 8 -N compounds with one- coordinate sulfur, e.g., dithionitrous acid (S=N-SH) and derivatives, the salts of the dithionitryl ion (1 +) ([S=N=S]+), and N-thionitroso-diorganyl-amines (S=NNR , R = organyl). Only the reac- 2 tions of [S=N=S]+ AsF5, among the known [S=N=S]+ salts, have been extensively studied. Cycloadditions with alkenes and triple bonded compounds produce 1 ,3,2-dithiazolium salts and their derivatives. S=NN(CH )z and S=NN(C H )z form transition metal complexes. The 3 6 5 Iigand is coordinated via the S atom in a monodentate manner.

• Autore: Norbert Baumann, Hans-Jürgen Fachmann, Reimund Jotter
• Editore: Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
• Collana: S. Schwefel. Sulfur (System-Nr. 9)
• Anno: 2013
• Rilegatura: Paperback / softback
• Pagine: 324 p.
• Dimensioni: 254 x 178 mm
• EAN: 9783662063538

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